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Beilstein J. Org. Chem. 2022, 18, 1100–1106, doi:10.3762/bjoc.18.112
Graphical Abstract
Figure 1: Plausible mechanism of the radical cation Diels–Alder reaction (EDG: electron-donating group).
Figure 2: Landscape of the radical cation Diels–Alder reaction.
Scheme 1: Radical cation Diels–Alder reaction of β-methylstyrene.
Scheme 2: Radical cation Diels–Alder reaction of β-methylanethole (1). Recovered starting material is reporte...
Figure 3: Formal expression of radical cations.
Scheme 3: Radical cation Diels–Alder reactions of the arylidene cycloalkanes (4–7). Recovered starting materi...
Scheme 4: Scope of the radical cation Diels–Alder reaction of arylidene cycloalkanes (recovered starting mate...